Forms of heavy metals within settling matter collected about once a month for 18 months, at each depth of water in a productive man-made lake, were examined by selective extraction using hydroxylamine-acetic acid (HA), hydrogen peroxide (HO), and hydrofluoric acid-nitric acid-perchloric acid (HF).
The largest portion of the metals was extracted with HA except for Fe, of which more than 80% was with HF. The amount extracted with HO was relatively small except for Cu. These amounts varied seasonally, showing distinctive patterns among fractions or metals.
These results and relationships among parameters suggest that the most important form is “adsorbed or coprecipitated on organic matter and hydrous Fe/Mn oxides.” Zn, Ni, and Cd are more associated with organic matter and Mn oxides, whereas Cu is more associated with Fe and Mn oxides. In case of Cu, firm bonding to organic matter is also significant.
The sedimenting processes of metals were suggested to be closely related to the cyclic behaviors of organic matter, Fe, and Mn within the lake.
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