In this paper, the effects of intensity of electron beam, detergent and colorant on creep rupture of polypropylene resin (PP), which is widely used in medicine containers, were investigated and the evaluation method of the long-term forecast of creep rupture was examined. Concretely, first, PP resins including colorant or not were prepared and samples that variously changed intensity of the electron beam irradiation were made. Creep rupture test of those samples was carried in detergent having various consistencies. The effects of those factors on creep rupture were considered and long-term forecast was tried by using time-temperature superposition principle about creep deformation. The following results were obtained.
(1) Although creep rupture of PP resin receives the effects of the presence of colorant, intensity of electron beam irradiation and detergent, the time-temperature dependence of creep rupture of PP resin including those affecting factors can be estimated by using the time-temperature superposition principle for creep deformation of the original PP resin. Based on this equivalency, it is possible to predict the long-term forecast of creep rupture of PP resin.
(2) Creep rupture is affected by the presence of colorant, intensity of electron beam irradiation and detergent and it happens earlier when the intensity of electron beam irradiation and consistency of detergent are increased.
抄録全体を表示