We investigated the influence of cold drawing, heat treatment, presence of oxidizing agents and cathodic protection on the susceptibility to stress corrosion of austenitic stainless steel wires. As the corrosive solution, boiling 42% MgCl
2 solution (154°C) was used in this test. The specimens were stressed in tention and measured the time to fracture. The results are as follows:
1) Influence of cold drawing; When 70% of the 0.2% proof stress are applied, the life to failure of stainless steel wires (0.5mm) decreases with the increase in degree of cold working up to 20% reduction, then increases with the increase in degree of cold working up to 40% or 95% redustion.
2) Effect of heat treatment; The specimens cooled rapidly after heating at 900°C in cracked NH
3 gas atmosphere or 1000°C in air, were relatively immune from susceptibility to stress corrosion, but the specimens cooled rapidly after heating at 1150°C in cracked NH
3 atmosphere, became remarkably susceptibile to stress corrosion. The times to fracture by stress corrosion of specimens annealed for one hour at 380°C after cold drawing were shorter than those of “as-cold drawn” specimens. The cold drawn specimens annealed at 650°C for 1.5 hours showed chromium carbide precipitation, but these specimens showed an improvement in stress corrosion resistance because of the stress relief by those heat treatment.
3) Effect of oxidizing agent; When a small quantity of KNO
3 as oxidizing agent was added to the corrosive solution, the fracture of these wires by stress corrosion did not occur.
4) Effect of cathodic protection; The cathodically protected specimens did not fail for 24 hours in the corrosive solution, when the current density exceeded 30μA/cm
2. The unprotected specimens failed within one hour.
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