The effects of the type of current waves and addition agents on the number of electrodeposited nuclei were investigated on the buffed cold rolled steel plates from the bath containing 60g/
l of stannous sulfate and 50g/
l of sulfuric acid.
(1) The effects of the type of current waves:
The number of electrodeposited nuclei increased very slightly according to the change of pulsating current, and it also depended on interrupting time (
T2) when interrupted current was used. Maximum number of nuclei was obtained for
T2=1sec in 1A/dm
2, or it was the value as large as 2.5 times of that in linear current. In P.R. current, the number increased with the increase in ratio (
Q) of the quantity of positive electricity (in coulomb) to that of negative one.
(2) The effects of addition agents:
The number of nuclei increased with the increase in the each addition amount of gelatine or β-naphtol. Gelatine was more effective than β-naphtol and the former gave the maximum number at the concentration of 0.5g/
l. When the above two agents were used together, the number was 7 times as large as the case of no agents by synergistic effects. When cresol sulfonic acid was used as an agent, a peak appeared at 100g/
l, as it had a different behavior from that of the above agents.
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