The influence of annealing atmosphere upon oxidation and descaling was studied to determine the annealing atmosphere most conducive to the descaling of stainless steel. Cold rolled SUS 430 and SUS 304 were annealed in a siliconit furnace which was set to 870°C and 1, 150°C, respectively, and which was filled with the exhaust gases generated from the burning of propane. The annealing atmosphere was changed by controlling the ratio of propane and air, and descaling was done by anodic electrolysis (4.0A/dm
2, 80°C, 40sec) in a solution of Na
2SO
4 (200kg/m
3, pH: 6.2). Specimens were then pickled in HNO
3-HF solution (14%-4%, 7%-2%) at 20°C or 60°C for 10sec. In SUS 430, the Cr depletion profile and descaling behavior varied with changes in the annealing atmosphere because the rate-determining step of oxidation was the diffusion of Cr through the oxide scale, whose composition and diffusion velocity of Cr was changed by the annealing atmosphere. Descaling of SUS 430 was very easy when it had been annealed in an atmosphere containing CO (carbon monoxide) or 0.2% O
2 and was relatively difficult when the annealing atmosphere containing over 1% O
2. In SUS 304, the Cr depletion profile was not changed by the annealing atmosphere because the rate-determining of oxidation was diffusion of Cr in the matrix, but the composition of oxide scale was changed depending on whether CO was contained in the atmosphere or not. Descaling was very difficult when SUS 304 had been annealed in an atmosphere containing CO, but was relatively easy when annealed in an atmosphere containing O
2.
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