This report has been drawn up as the result of fundamental studies on mass transfer in the centrifugal gas-liquid contactor in which liquid is spouted from the small holes drilled through a rotating cylinder wall, and where gas is sent cross-currently to the water jets in an annular space between the rotating cylinder and a stationary concentric outside cylinder.
Many experiments on pure CO
2 gas absorption by water jets spouting from rotating small holes were carried out at 20°C, and the effects of the following variables on the liquid mass transfer rate were studied: diameter of the rotor, diameter of the small hole, number of the small holes, width of the annular space, gas flow rate, liquid flow rate, revolution of the rotor, time of contact, etc.
In these experiments, the diameter of the small hole was 0.52.0mm, the average velocity of water, 55950cm/sec, and the travelling length of water (the distance between two cylinders), 15cm. Under these conditions, the water jet might present laminar flow. Therefore, assuming that the concentrations of gas and liquid were equilibrium on the interfacial surface, the mass transfer coefficient of the liquid film,
kL, was defined by a well-known Eq. (10), derived theoretically from the unsteady-state diffusion theory. The contact area per unit volume of water jet,
a [cm
2/cm
3], and the liquid film capacity coefficient,
kLa [1/sec], was obtained experimentally.
As the result, the following equations were derived:
kLa=2
a√
DL/πθ=
EML/θ
a=0.0875(
DL/πθ)
-1/2(
d-1.2)(
r1n/ω)
β=36.5(
d-1.2)(
r1n/ω)
βWhere β=0.72 for
d≥1.0mm
=3.93
d0.74 for
d<1.0mm
The gas absorption rate by water was observed to be large immediately after the liquid was spouted from the hole, as is obvious from above equations. Therefore, for the practical designing of this kind of contactor, it would be advisabe to prepare a multi-rotor-type contactor in order to make many jets of liquid as possible.
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