From the simplified model in which the liquid is supposed as a dense system com posed of rigid molecules, the equation of liquid thermal conductivities has been derived as the func-tion of their densities. ument, it is considered that the change of transport coeffi cients of liquids depends free distance during molecules.
The equation derived here contains two par ameters and can be written as, (1) where, α
1=1/
K1ρcTc1/2 and
bTk3=ρ
c/ρ
ok, respectively. Two parameters, α
1 and
bTk3, related to each sub- stance are nearly independent perature and pressure.
The performance of the equation was examin ed on more than 276 point s of data on 22 kinds of liquid s and the deviation of easured or recommended values was less than 4% with the exception of NH
3 and the average deviation was less than 0.8% for the range of 0.45≥
Tr≥0.9.
The numerical values of
bTk3 are found so clos e to 0.76 (
ρc/ρm) independently of the kinds of substa nces that the equation (1) can be actually expected to be used as one parameter. The temperature dependence of thermal conductivity is so considered.
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