Shimajiri marl, which occurs widely in the southern part of Okinawa Island, is a bluish-gray soft rock. It is recognized that major minerals of soil derived from the marl are montmorillonite, kaolinite, illite and chlorite. Based on the analogy with the fine sand found in marl soil, primary rock minerals found in marl are assumed to be feldspar, calcite, dolomite, gypsum, pyroxene, halite and so forth.
These primary minerals react with CO
2-containing waters in the marl area. Chemical constituents such as Ca
2+, Mg
2+, Na
+, K
+, HCO
3-, CI
-, SO
2-4 and soluble SiO
2 are dissolved from the minerals to natural waters, and eventually the above clay minerals are formed. As one example of chemical weathering of rock forming minerals, the following equation may be used.
5MgSiO
3+CaAl
2Si
2O
8+2CO
2+5H
2O
Mg
5Al
2Si
3O
1010(OH)
8+Ca
2+2HCO
3-+4SiO
2By solving these equations for weathering, the amounts of weathered silicate minerals and of formed clay minerals as well as primary minerals can be calculated, when the concentrations of chemical constituents in natural waters are put into the equations.
Thus, the results obtained for the Shimajiri marl area are as follows :
Primary rock minerals weathered : 350 (t·km
-2·y
-1)
Clay minerals formed : 120 (t·km
-2·y
-1)
Chemical species released : 340 (t·km
-2·y
-1)
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