The concentrations and the enrichment factors for Fe, Mn and organic matter in suspended solids, which are scavengers of trace metals in the water, were found to be slightly higher in estuarine water than in rivers, suggesting adsorption of trace elements on particles. In addition, concentrations of trace elements such as Pb, Cu, Zn, Ni, Mn, Cr, Co and P in suspended solids in water column and in the sieved sediments were positively correlated with the amount of organic matter at p=0.1% (n=59, r=0.66-0.89). As to trace elements dissolved in the water, the concentrations of Fe, Cu, Ni, Pb and Cr in estuarine surface waters were slightly lower than in river waters, but Mn, Ag and Zn showed the reverse tendencies. The comparison of concentrations of trace elements in the interstitial water obtained from estuarine sediments with the overlying water indicates a characteristic increase of Mn and Co by factors of 620 and 37, respectively, and a 7.3-15 fold increase of Cr, Cu, Zn, Pb, Ag, Fe and Ni.
Thus, it was found that trace elements carried from river to estuary in the form of suspended solid and dissolved state are removed in small quantities from the water column mainly by flocculation together with organic matter, and again released into the environment from the sediment.
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