The prediction in temperature of the sliding surface is one of the important issues so as to estimate the wear amount of polymeric materials such as polyacetal. For this purpose, it is essential to measure the critical sliding velocity or limiting PV values corresponded to both material properties and shape of test specimens. The limiting PV values have been measured only under a single sliding geometry in many cases, owing to the difficulty in applying different sliding geometries. In this study we discussed the influence of the sliding geometries on the limiting PV values of polyacetal and showed the total sliding area and dynamic friction coefficients were closely related to the limiting PV values.