Journal of the Japan Petroleum Institute
Online ISSN : 1349-273X
Print ISSN : 1346-8804
ISSN-L : 1346-8804
Volume 59 , Issue 1
Showing 1-5 articles out of 5 articles from the selected issue
Regular Paper
  • Tadashi SAWAI, Takahiro YONEHARA, Makoto SANO, Toshimitsu SUZUKI, Taka ...
    Type: Regular Paper
    2016 Volume 59 Issue 1 Pages 1-8
    Published: January 01, 2016
    Released: March 01, 2016
    JOURNALS FREE ACCESS
    Metal-organic framework (MOF) compounds consisting of terephthalic acid and cations (Cr3+, In3+, Al3+, Cu2+ and Zn2+) were prepared by the hydro- and solvo-thermal methods and characterized by XRD, N2 adsorption-desorption isotherm, TG-DTA and FE-SEM. The prepared MOFs were crystalline and phase-pure. MOFs were used as column packings for chromatographic separation of alkylbenzenes. MOFs recognized differences in molecular sizes in addition to boiling points of alkylbenzenes. Activation energy for diffusion in the MOF micropores ranged from 25 to 60 kJ mol−1. Temperature-programmed XRD measurement in air revealed that no expansion or contraction of MOF frameworks occurred up to 230 °C.
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  • Akihisa KITA, Kounosuke KOBAYASHI, Toyokazu MIURA, Yoshiko OKAMURA, Ts ...
    Type: Regular Paper
    2016 Volume 59 Issue 1 Pages 9-15
    Published: January 01, 2016
    Released: March 01, 2016
    JOURNALS FREE ACCESS
    High-rate production of methane from acetate using a fixed-bed reactor filled with marine sediment containing halotolerant aceticlastic methanogens and 3 % NaCl was investigated. In continuous culture, the methane production rate increased with increasing dilution rate. The maximum methane production rate of 750 mM d−1 was observed at a dilution rate of 16.2 d−1, which is impossible without immobilization of the cells in the sediment. Using scanning electron microscopy, we observed Methanosaeta-like filamentous microorganisms and Methanosarcina-like coccoid microorganisms in granule-like structures. The results demonstrated that marine sediment is not only a promising microbial resource of halophilic aceticlastic methanogens, but also a supporting material to fix aceticlastic methanogens in a fixed-bed reactor.
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  • Takanori SAEKI, Kensaku TSUDA, Hironobu OHKITA, Noriyoshi KAKUTA, Taka ...
    Type: Regular Paper
    2016 Volume 59 Issue 1 Pages 16-23
    Published: January 01, 2016
    Released: March 01, 2016
    JOURNALS FREE ACCESS
    We investigated the effects of the Ni : Cu ratio and metal loading of a CeO2-supported bimetallic Ni–Cu catalyst on its reduction behavior and catalytic performance during steam reforming of ethanol for H2 production. Compared with monometallic Ni and Cu catalysts, both the NiO and CuO phases in the bimetallic catalysts were reduced at lower temperatures to form fine NiCu alloy crystallites. At a reaction temperature of 673 K, Ni/CeO2 exhibited a higher H2 yield than Cu/CeO2 but also produced a large quantity of CH4 and carbon deposits. The undesired byproducts were substantially inhibited by replacing a portion of the Ni with Cu. The highest H2 yield and an excellent carbon inhibition were achieved when the content of each metal was 5 wt%. Notably, a physical mixture of Ni/CeO2 and Cu/CeO2, each with the same metal contents, exhibited a lower H2 yield and heavy carbon deposition. This indicates that the higher reducibility and alloying in the bimetallic catalyst are key factors for synergistic improvements of the catalytic properties.
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  • Hiromi MATSUHASHI, Daichi FUNAKI
    Type: Regular Paper
    2016 Volume 59 Issue 1 Pages 24-30
    Published: January 01, 2016
    Released: March 01, 2016
    JOURNALS FREE ACCESS
    Solid-base catalysts consisting of CaO covered with 5-20 mol% TiO2 (TiO2/CaO) were prepared by deposition of titanium tetraisopropoxide (Ti(OCH(CH3)2)4) on a Ca(OH)2 surface in an ethyl acetate solution, followed by thermal decomposition in air at 773-1073 K for 3 h. The catalyst heated at 773-973 K showed higher activity for the base catalyzed retro-aldol reaction to convert diacetone alcohol (4-hydroxy-4-methyl-2-pentanone) to acetone at 299 K. 10 mol% TiO2/CaO heat-treated at 773 K was the most active catalyst for the retro-aldol reaction among the metal oxide-covered CaO catalysts. The catalyst treated at 1073 K was inactive for the same reaction, as was uncovered CaO. The catalytic activity of TiO2/CaO poisoned by water was recovered by washing with acetone, confirming that TiO2-covered CaO had sufficient stability against H2O. No leaching of Ca2+ into the polar solvent diacetone alcohol was observed in any covered catalyst.
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