Journal of Synthetic Organic Chemistry, Japan
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
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Volume 79, Issue 10
Displaying 1-6 of 6 articles from this issue
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Preface
Reviews and Accounts
Review de Debut
  • Open-cage Fullerenes as Ligands
    Mitsuaki Suzuki
    2021 Volume 79 Issue 10 Pages 968-970
    Published: October 01, 2021
    Released on J-STAGE: October 08, 2021
    DOIhttps://doi.org/10.5059/yukigoseikyokaishi.79.968
    JOURNAL OPEN ACCESS
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    Fullerene chemistry can be divided into “outer”, “inner” and “skeletal” chemistry. “Outer chemistry” is the chemical modifications of fullerenes, and “Inner chemistry” is the chemistry of endohedral metallofullerenes. “Skeletal Chemistry” is represented by the synthesis of a heterofullerene in which the carbon atom of fullerenes is replaced with a heteroatom such as a nitrogen atom, and the synthesis of an open-cage fullerene having an opening site inserted into a skeleton of fullerenes. The open-cage fullerene having a hetero atom in the opening site are expected to be used as ligands having a widely distorted π-conjugated system. In this mini-review, open-cage fullerenes inserted into metal complexes as ligands are introduced from recent studies.

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