Journal of the Ceramic Association, Japan
Online ISSN : 1884-2127
Print ISSN : 0009-0255
ISSN-L : 0009-0255
Volume 72, Issue 824
Displaying 1-13 of 13 articles from this issue
  • Toshio MAKI, Megumi TASHIRO
    1964 Volume 72 Issue 824 Pages 107-109
    Published: July 01, 1964
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
    The firing range of petalite ceramics can be extended markedly by the addition of powdered lithia glass (Li2O 10.7, MgO 8.9, Al2O3 8.9, SiO2 71.5wt. %) to petalite powders in a weight ratio of 1:9 (M. Tashiro and T. Maki, J. Ceram. Assoc. Japan, 70, 8 (1962); M. Tashiro and T. Maki, J. Ceram. Assoc. Japan, 71, 65 (1963); T. Maki and M. Tashiro, J. Ceram. Assoc. Japan, 71, 196 (1963)). In the present study, slip preparation most feasible for this nonplastic mixture was studied. The most stable slip composition determined was petalite 90, lithia glass 10, bentonite 5, and carboxymethyl cellulose (CMC) 0.02 in weight ratio. The raw materials were ball-milled in water to the fineness of almost less than 5μ in diameter. The optimum water content was 35% (wt.) of the wet base. When the bentonite content exceeded the above value, slip-cast specimens shrunk more than 27% in volume on firing. CMC was effective not only as a floating agent but for increasing the mechanical strength of dried slip-cast specimens. The modulus of rupture of 900kg/cm2 was attained in the slip-cast specimen fired at 1250°C for one hour.
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  • Kazuo OOKA
    1964 Volume 72 Issue 824 Pages 110-115
    Published: July 01, 1964
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
    Recently electric boosting technique using molybdenum electrode is often applied in glass melting. In this paper, studies on effects of temperature and composition of glasses on corrosion of molybdenum are reported.
    In the first experiment molybdenum test pieces were immersed in various kinds of molten glasses, namely, borosilicate, aluminosilicate, soda-lime-magnesia, barium or lead glasses for 50 hours at 1400°C, and in the second, effects of refining agents such as As2O3, Na2SO4 and Sb2O3 were examined by 50 hours' soaking at temperatures from 1100° to 1500°C.
    Visual observation of molybdenum test pieces and glasses after the corrosion test and determination of weight loss of molybdenum showed that;
    1) Weight loss of molybdenum increased with rising the soak temperature.
    2) Weight loss of molybdenum increased distinctly with the amount of As2O3 and slightly with Na2SO4, and the effect of Sb2O3 was almost unrecognizable.
    3) In the corrosion test with lead containing glasses, test pieces were corroded severely and contamination or devitrification of glasses and separation of metallic lead from glasses were observed.
    4) In the corrosion test with other kinds of glasses, contamination of glasses occured only around test pieces. Effects of major components except PbO were considerably small.
    5) Corrosion products on the surface of test pieces were MoO3, MoO2+MoO3, Mo+MoO2 or in case of SO3-- containing glasses (reducing condition), MoS2. The authors are of opinion that the corrosion of molybdenum is presumably accelerated by formation and evaporation of MoO3.
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  • Shigetomo MATSUO, Kazumoto HOMMA
    1964 Volume 72 Issue 824 Pages 115-118
    Published: July 01, 1964
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
    It is considered that the emissivity, one of thermal properties, is an important charcteristic to be measured as well as electrical and mechanical properties in exploring and developing MoSi2 as a heating element.
    We measured the spectral emissivity of MoSi2 in the temperature range between 800°C and 1700°C for the wave length of 0.65μ.
    The method of the measurement is as follows.
    A cylinderical sample of MoSi2 is placed horizontally in a vacuum vessel and heated radially by a Mo heating element that is placed at the center of the sample.
    The temperature of the sample is measured at the bottom of several pores of different depths, previously drilled on the wall of the cylindrical sample.
    Since the thermal conductivity is approximately constant throughout the sample, the true temperature at the outer surface of the sample, T, can easily be obtained from measurements of Ta and Tb, the temperature at the distance γa and γb from the center of the cylinder respectively, by extrapolation.
    Using the true temperature T and the apparant temperature TB, the emissivity, Eλ, can be calcurated by the equation; log Eλ=9.62×10(1/T-1/TB).
    The result obtained is as follows. The emissivity is 0.83 at 800°C, takes the minimum value of 0.75 at 1150°C and increases herefrom with temperature to reach 0.87 at 1700°C.
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  • Keiji KOBAYASHI, Ryosuke YOKOTA
    1964 Volume 72 Issue 824 Pages 118-122
    Published: July 01, 1964
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
    The crystal structure of tellurite (TeO2) is similar to that of titanium dioxide which has high dielectric constant. TeO2-containing glasses which have antisymmetrical (TeO6) octahedra, as in the case of tellurite, show peculiar dielectric properties, namely, high dielectric constants and low dielectric losses. According to an experiment by Stanworth, however, thermal expansion of these glasses is very large, softening temperature or mechanical strength are low, and chemical durability is poor. In this paper, results are reported on experiments to improve electrical and mechanical properties by finding new glass forming regions in the system TeO2-Ba(PO3)2-RPO3(R=Li, Na, K). Rather stable glasses were obtained. Physical properties and chemical durability were considerably satisfactory except for glasses of high potassium content. At a room temperature dielectric constant and dielectric loss for 1Mc/sec is 15-26 and 0.002-0.008 respectively. Thermal expansion coefficients are 120-166×10-7/°C (from room temperature to 200°C) and softening temperatures are 380°C-430°C. Relations between dielectric properties and glass structure are discussed.
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  • 1964 Volume 72 Issue 824 Pages A39-A44
    Published: July 01, 1964
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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  • [in Japanese]
    1964 Volume 72 Issue 824 Pages C525-C529
    Published: July 01, 1964
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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  • [in Japanese]
    1964 Volume 72 Issue 824 Pages C530-C538
    Published: July 01, 1964
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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  • 1964 Volume 72 Issue 824 Pages C539-C542
    Published: July 01, 1964
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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  • [in Japanese]
    1964 Volume 72 Issue 824 Pages C543-C546
    Published: July 01, 1964
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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  • 1964 Volume 72 Issue 824 Pages C546
    Published: July 01, 1964
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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  • [in Japanese]
    1964 Volume 72 Issue 824 Pages C547-C550
    Published: July 01, 1964
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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  • 1964 Volume 72 Issue 824 Pages C551-C554
    Published: July 01, 1964
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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  • 1964 Volume 72 Issue 824 Pages C565-C568
    Published: July 01, 1964
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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