Journal of the Ceramic Association, Japan
Online ISSN : 1884-2127
Print ISSN : 0009-0255
ISSN-L : 0009-0255
Volume 80, Issue 924
Displaying 1-7 of 7 articles from this issue
  • Toru MATSUSHITA, Iwao YAMAI
    1972Volume 80Issue 924 Pages 305-312
    Published: August 01, 1972
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
    The optimum calcination for the Sb2O3-doped SnO2 ceramics was obtained at 1000°C for 2 to 4hrs. The solubility of Sb2O3 in SnO2 was 20 to 25wt% under the calcinating conditions. Lattice constants of the Sb-doped SnO2 ceramic specimens were decreased up to 15% Sb2O3 and increased above 15% Sb2O3. Their density was increased up to 10 to 15% Sb2O3 and decreasd above 15% Sb2O3. Sintering of the ceramic specimens was markedly promoted by the addition of ZnO, MnO2, or CuO with the best. It is assumed that the addition of ZnO or MnO2 produces a substitution of Sn4+ ions in the SnO2 lattice. These substitutions give a charge unbalance creating oxygen vacancies. The CuO addition causes a liquid phase sintering. It is conjectured that both of the oxyen vacancies and the liquid phase promote sintering. High density of the ceramic specimens gives high flexural strength. Electrical resistivities of the Sb2O3-doped specimens with ZnO were 5 to 50Ω-cm and those of the Sb2O3-doped ones with CuO, 1 to 104Ω-cm at room temperature. Those of the Sb2O3-doped ones with MnO2 were extremely high.
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  • Relationship between Slip Properties and the Fundamental Parameters of Whiteware Bodies
    Nobuhiko WATANABE
    1972Volume 80Issue 924 Pages 313-318
    Published: August 01, 1972
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
    Viscosity of casting slips, casting rate and thickness of remaining slip layer on draining were investigated to obtain equations expressed as functions of fundamental parameters, i.e. solid fraction (F3), specific surface area (Sa) and hydration degree of solid (ds). The results were summarized as follows.
    (1) Viscosity of slips could be given by the equation η=I(AF32/3)Saf(d/ds), where (AF32/3)Sa and f(d/ds) related to the contact area of particles and the binding force at contact points depending on water film thickness d, respectively. Viscosity coefficient (I) was found to be rather constant except slips with different type of flow curves.
    (2) Casting rate could be calculated from the viscosity and the fundamental parameters. The reliability depended largely upon accuracy of the measured viscosity.
    (3) The thickness of remaining slip layer on draining could be expressed by the equation Δl=θ/(ρsgsinα), where ρs, θ and α denoted slip density, yield value and draining angle, respectively.
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  • Shinsuke HAYASHI, Hajime SAITO
    1972Volume 80Issue 924 Pages 319-323
    Published: August 01, 1972
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
    Fibrous magnesia crystals were grown via vapor phase, by means of oxidation of magnesium vapor with moisture. Magnesium vapor was made from the reduction of MgO with CaC2. The results obtained were as follows:
    1) The morphology of crystals obtained mainly depends on the quantity of water diffusing into the crystal growth region. The crystal changes its form from fibrous polycrystal to whisker-like crystal, and finally to bulk crystal with increase of water vapor.
    2) The growth axis of whisker-like crystal has mainly ‹100› direction. The axial growth is restricted by the two-dimensional nucleation on the prism faces of the crystal. Tensile strength of whisker-like crystals increases with decreasing cross section. A value of 100kg/mm2 was measured from a crystal of 5μ in diameter.
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  • Ken ANDO, Yasumichi OISHI
    1972Volume 80Issue 924 Pages 324-326
    Published: August 01, 1972
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
    The self-diffusion coefficient of oxygen ion in a single crystal of MgAl2O4 has been measured in the temperature range of 1420° to 1630°C by a gas solid exchange technique utilizing O18 as a tracer. The temperature dependence of the self-diffusion coefficient was expressed by the equation:
    D=1.5×103 exp(-36×103/RT) cm2/sec,
    which was interpreted to be due to intrinsic diffusion. The determined self-diffusion coefficient of oxygen ion was smaller by several orders of magnitude than that of magnesium ion in MgAl2O4 and was close to the apparent diffusion coefficients calculated from the sintering rate of MgAl2O4.
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  • Yoichi OYAMA, Osami KAMIGAITO
    1972Volume 80Issue 924 Pages 327-336
    Published: August 01, 1972
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
    Sintering by hot-pressing of the system, Si3N4-Al2O3, was investigated.
    The purities of the raw materials were about 98.5% for Si3N4 and 99.99% for Al2O3. Their grain sizes were, both, about 1μ in diameter. Temperature, time and pressure in the hot-pressing were 1650°-1850°C, 6-60min and 250kg/cm2, respectively.
    The following results were obtained. The quantity of Al2O3 necessary for full densification of the mixture Si3N4-Al2O3 was more than 20mol%, which agreed with that given by Deeley et al. Grain-growth in the sintered body was observed to be remarkable when Al2O3-concentration exceeds 40mol%. The activation energies for sintering under the pressure of 250kg/cm2 were determined to be 100kcal/mol for 80mol% Si3N4-20mol%Al2O3 and 67kcal/mol for 60mol% Si3N4-40mol% Al2O3. Oxidation resistance of sintered Si3N4-Al2O3, evaluated by the weight gain, increased with Al2O3-concentration, reaching the maximum at 65mol% of Al2O3, followed by decreasing when Al2O3-concentration exceeds 65mol%. At the Al2O3-concentration of 65mol%, the oxidation resistance was more than 10 times as high as that of the system, Si3N4-MgO. Abrasive resistance of the sintered body, evaluated by the weight-loss during a abrasive test with abrasive powder, SiC #800, increased with Al2O3-concentration, reaching the maximum at the Al2O3-concentration of 50mol%, followed by decreasing when Al2O3 concentration exceeds 50mol%. The maximum abrasive resistance was about 4 times as high as that of sintered 85mol% Si3N4-15mol% MgO, which is in practical use.
    By hot-pressing, the solid solution of Si3N4 and Al2O3, Si3N4ss, was found to be formed, which was already pointed out by the present authors. The solubility limit of Al2O3 in Si3N4s.s. was estimated to be about 67mol% at 1750°C and 78mol% at 1850°C. From the observation of specific gravity of Si3N4ss, the solid solution is thought to be of a substitutional type. A new compound was also found, whose composition was estimated to be 2Si3N4⋅3Al2O3. The new compound was stable under slightly oxidizing atmosphere and unstable under neutral or slightly reducing atmosphere. The eutectic point in the system was estimated to be 1870°±30°C. An approximate phase diagram was given for Si3N4-Al2O3.
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  • Akira YAMAGUCHI, Etsuro KATO
    1972Volume 80Issue 924 Pages 337-339
    Published: August 01, 1972
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
    Anhydrous magnesium sulfate exists in two monotropic forms and its transition point 595°±5°C. The data of the lowtemperature form correspond to that reported by P. J. Rentzeperis et al.
    The high-temperature form is orthorhombic and its lattice constants 4.750, 8.589 and 6.703Å.
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  • 1972Volume 80Issue 924 Pages A53-A60
    Published: August 01, 1972
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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