To clarify the characteristics of stream chemistry in Tatsunokuchi Hydrological Station (THS) in Okayama City. Okayama Prefecture (lat E133°58', long N 34°42'), we observed the chemistry of streamwater in the Kitadani and the Minamidani catchments at THS. The concentrations of constituents evaluated were extremely high compared with those in the other streams in Japan. The concentrations of Ca2+, Mg2+, Na+, HCO-3 and Cl- abruptly decreased with increased discharge whereas the concentration NO-3, total nitrogen (T-N) and dissolved organic carbon (DOC) showed rising peaks after rain events. The high concentrations of constituents in the streams were explained by the concentration by evapo-transpiration and the dissolution from geology such as basic rocks. We estimated that water stored was small in the catchments after rain event in THS so that the concentration by evapo-transpiration was strong and the streamwater of high constituent concentrations was produced at no rainy days. In rain events, the constituent concentrations in the streams decreased by direct flow with low concentrations, but NO-3, T-N and DOC increased due to the leaching from surface soils. The concentrations of Ca2+, Mg2+, HCO-3, Cl- and So2-4 were higher in Kitadani catchment than Minamidani catchment in THS and pH and the concentrations of Na+, NO-3 and SiO2 were higher in Minamidani catchment. The difference of the inclination of the slope and the geology between two catchments might have effected the constituent concentrations in the stream waters.
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