Hydrodynamic dispersion coefficients,
D, for an aggregated Andisol were determined for saturated and unsaturated flow conditions. The dispersivities,
λ, as a function of pore-water velocities,
v, and volumetric water contents,
θ, were compared with those for a non-aggregated dune sand. The water retention curve for the Andisol had a stepwise shape. The water content decreased drastically at air-entry
h=-15 cm and lower pressure head
h=-3,160 cm. The radius of the aggregate was assumed to be approximately 0.1 mm based on the air-entry value. The estimated
θ for the aggregate were 0.5 cm
3 cm
-3 while the saturated water content was 0.74 cm
3 cm
-3. The dispersivity,
λ, increased linearly with
v and reached more than 2 cm for saturated water flux,
q, ranging from 146 to 3,085 cm d
-1. This velocity dependency was due to solute exchange between inter-and intra-aggregate pores. The convection-dispersion equation (CDE) agreed well with measured breakthrough curves (BTCs) regardless of
q values because of the relatively rapid solute exchange. On the other hand,
λ for unsaturated conditions decreased as
θ decreased from saturation, and had a constant value of 0.2 cm for
θ=0.5-0.6 cm
3 cm
-3. Effects of water flow in inter-aggregate pores decreased and flow in intra-aggregate pores became dominant for lower
θ. The CDE also agreed well with unsaturated BTCs because of relatively homogeneous flow in the soil aggregates.
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