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Volume 17, Issue 11
Displaying 1-10 of 10 articles from this issue
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Masanori OKUYAMA1996 Volume 17 Issue 11 Pages 648-653
Published: November 10, 1996
Released on J-STAGE: August 07, 2009
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Shinji NAMBU1996 Volume 17 Issue 11 Pages 654-659
Published: November 10, 1996
Released on J-STAGE: February 05, 2010
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Tsuyoshi HORIKAWA1996 Volume 17 Issue 11 Pages 660-665
Published: November 10, 1996
Released on J-STAGE: February 05, 2010
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Takashi NAKAMURA1996 Volume 17 Issue 11 Pages 666-670
Published: November 10, 1996
Released on J-STAGE: August 07, 2009
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Application to Surface Acoustic DeviceNorifumi FUJIMURA, Taichiro ITO1996 Volume 17 Issue 11 Pages 671-675
Published: November 10, 1996
Released on J-STAGE: February 05, 2010
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Keiichi NASHIMOTO1996 Volume 17 Issue 11 Pages 676-682
Published: November 10, 1996
Released on J-STAGE: February 05, 2010
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Decomposition and Oxidation of Methanol and Formic Acid and Partial Oxidation of Butane on Pd SurfaceKoji WATANABE, Hisashi OHNUMA, Kazuya NAGAO, Hiroshi UETSUKA, Kimio KU ...1996 Volume 17 Issue 11 Pages 683-687
Published: November 10, 1996
Released on J-STAGE: February 05, 2010
JOURNAL FREE ACCESSThe infrared chemiluminescence technique was applied to catalytic oxidation of CH3OH, HCOOH and i-C4H10 on a Pd surface, and the reaction dynamics and mechanism were discussed in terms of internal energy states of nascent product CO2 and CO molecules. The vibrational and rotational states of CO2 produced by CH3OH oxidation were quite similar to those of CO2 produced by CO oxidation, indicating that the final step of the CO2 formation in the CH3OH oxidation involved a bimolecular process (i.e., COad+Oad). On the contrary, the intensity of IR emission of CO2 produced by HCOOH oxidation was very weak, suggesting that most of CO2 was not so vibrationally excited and that CO2 was formed via decomposition of HCOOad (unimolecular decomposition of formate). The selective production of CO and H2O was observed by the partial oxidation of i-C4H10 on Pd, and the vibrational state of product CO was very different between the Pd and Pt surfaces. These differences in internal energy states of the CO and CO2 products can provide us with new information on the dynamics and mechanism of catalytic reactions.View full abstractDownload PDF (634K) -
Kiminori KAKITANI, Yoichiro YAGI, Akio YOSHIMORI1996 Volume 17 Issue 11 Pages 688-693
Published: November 10, 1996
Released on J-STAGE: February 05, 2010
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Mitsunori SAITO1996 Volume 17 Issue 11 Pages 694-697
Published: November 10, 1996
Released on J-STAGE: August 07, 2009
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The Know-how for the Construction of AFM and Image InterpretationSeizo MORITA, Yasuhiro SUGAWARA, Masahiro OHTA1996 Volume 17 Issue 11 Pages 698-700
Published: November 10, 1996
Released on J-STAGE: August 07, 2009
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