Zero point of charge (ZPC) is a point, where the net charge of variable charge components is zero deu to the equal H^+ and OH^- adsorption on them. σ_p is the remaining charge at ZPC, and both organic and mineral components that are capable of adsorbing H^+ or OH^- at ZPC contribute to the value of σp. ZPC is, therefore, a specific value for variable charge soils, and considered to be very important as a measure for the evaluation of those soils. In this paper, many aspects of 36 variable charge soils from Thailand and Japan were discussed with special reference to ZPC; a), study background, b). theoretical background, c). determinative factors, d). reactivity of the particles, e). type of the titration curves with respect to buffering capacity, specific surface area, exchangeable aluminum, organic matter, 2:1 clay minerals with permanent negative charge, and the possibility to utilize ZPC value for the fertility management and conservation, f). distribution within the pedon. Furthermore, pedological feature of ZPC, namely, ZPC distribution within the pedon and its fluctuation accompanied with the chemical weathering, were discussed. Above, all, specific surface area (SSA) together with ZPC would be a key property, when considering a intense weathering in the tropics. SSA would increase with weathering initially, then followed by a gradual reduction to low values in the final stages of weathering. On the other hand, the ZPC value would shifted toward a lower pH initially, accompanied with the formation of 2:1 clay minerals, and as further desilication process going on and subsequent formation of 1:1 clay minerals, it would shift back again toward a higher pH. Finally, its value became as high as that of the iron and aluminum oxides when the basic rocks were the parent materials and iron and aluminum oxides were the only residual source of charge, or became lower when the sandy materials were the parent materials and silicious oxide as a form of qualtz alone was accumulated. It could be concluded that, at the final stage of weathering, the SSA value would decrease, while the ZPC value would converge toward different direction, depending on the nature of the parent material.
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