Journal of The Adhesion Society of Japan
Online ISSN : 2187-4816
Print ISSN : 0916-4812
ISSN-L : 0916-4812
Volume 41, Issue 4
Displaying 1-4 of 4 articles from this issue
Review
Short Communication
Technical Report
  • Naoki YOKOYAMA, Kiyokazu YONEKURA, Masashi KAJI
    2005 Volume 41 Issue 4 Pages 137-142
    Published: April 01, 2005
    Released on J-STAGE: November 30, 2014
    JOURNAL FREE ACCESS
    Epoxy resin compounds modified with aromatic olefin oligomers for electronic materials were prepared and the properties were studied. Cured compounds modified with aromatic olefin oligomers have been found to be decreased water-absorbing capacity and dielectric constant. As aromatic olefin oligomers, styrene oligomers and indene oligomers were synthesized. Properties of cured systems with indene oligomers were better than that with styrene oligomers, i.e., linear expansion of cured systems with indene oligomers was lower than that with styrene oligomers, and temperature of inflection point in TMA of the former was higher than that of the latter. The phase structures of cured systems were analyzed by relationships between tanδ and temperature. As the results, we found that water-absorbing capacity and dielectric constant of cured systems with indene oligomers decreased without decrease of linear expansion. We considered that the reason why cured systems with indene oligomers showed above good properties was due to the rigid molecular structure of indene oligomers and the good compatibility to cured epoxy resin matrix.
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Original Paper
  • Kazuyoshi EBE, Hideo SENO, Takashi SUGINO, Osamu YAMAZAKI
    2005 Volume 41 Issue 4 Pages 128-136
    Published: April 01, 2005
    Released on J-STAGE: November 30, 2014
    JOURNAL FREE ACCESS
    Thispaperisconcernedwithbondingstrengthoftheadhesivetapecomposedofanacryliccopolymer,mixedepoxyresinsanddipentaorithrytolhexaacrylate(DPHA),whichisapplicabletodicinganddiebondingthereafter.Investigatedweretheeffectsoftheexposuredoseofultra-violetlight(UV)beforedicingandtheamountsofDPHAonthebondingstrengthbetweenthermallycuredadhesivecompoundandthecoppersubstrateasthemodelfoi、oil℃uits・IncaseswhereeitheroftheexposureandDPHAwaswithin400mJ/cm-or10partsofothercomponents.respectively,the90peelstrengthwasstrongenoughexceeding6N/cm.ThestoragemodulusatiOU℃,theinitialbondingtemperature,wasbelow4x10'Paevenforthecasesofpooradhesion,indicatingenoughwettabilitytothesubstrate.However,theX-rayphotoelectronspectrometry(XPS)takenatatake-offangleof45ontheinterfacelayerofadhesivesprovedthattheoxygen/carbonatomicratio(O/C)was0.36beforeUVexposureandthendecreasedto0.27uponexposureto780mJ/cm-resultinginverypooradhesion.ThetendencyofdecrementofoxygenatomsintheinterfacewasalsoobservedinthecaseofhigherDPHAcontentthan10parts.Itwasthereforeconcludedthatthebondingstrengthlargelydependsonthechangeindistributionofoxygenatomsorpolargroupsintheinterfacelayet・duringUVcuringofDPHA.
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