Netsu Bussei
Online ISSN : 1881-414X
Print ISSN : 0913-946X
ISSN-L : 0913-946X
Volume 30, Issue 3
Displaying 1-2 of 2 articles from this issue
  • Naoki Matsunaga, Mohd Syafiq Aswad bin Mohd Rozin
    2016 Volume 30 Issue 3 Pages 125-130
    Published: 2016
    Released on J-STAGE: December 02, 2016
    JOURNAL FREE ACCESS

    Using the apparatus for the measurement of gaseous diffusion coefficients D by the Stefan method described in the first report, the diffusion coefficient of diethyl ether vapor into dry air was measured at 298.15 K (25°C)and at atmospheric pressure. The diffusion path lengths L(≅ 80×10-3 m, 120×10-3 m, 160×10-3 m) and the air flow rates Q (0.8×10-6 m3s-1 -42×10-6 m3s-1 (50 cm3min-1-2500 cm3min-1)) were systematically changed as in the first report. A loose polyester cotton plug was inserted into the horizontal tubing just upstream of the mouth of the evaporation tube to straighten air flow. The present results were compared with those in the first report obtained at 303.15 K (30°C). The air flow rate Q suitable to the measurement (5×10-6 m3s-1 -16×10-6 m3s-1 (300 cm3min-1000 cm3min-1)) was found to be lower than that for 303.15 K. The range of the air flow rate Q suitable to the measurement was narrowed with increasing diffusion path length L. Both the present experimental value (D = 0.091×10-4 m2s-1) and that at 303.15 K in the first report agree well with the extrapolation of our experimental data obtained by the Taylor dispersion method to lower temperature.

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  • Syou Maki, Seiji Fujiwara, Ryunosuke Maekawa, Seiichi Tanaka, Masayuki ...
    2016 Volume 30 Issue 3 Pages 131-139
    Published: 2016
    Released on J-STAGE: December 02, 2016
    JOURNAL FREE ACCESS

    By using simultaneously the magnetic levitation technique and the transient short hot wire method, thermal conductivity and diffusivity of hen egg-white lysozyme (HEWL) crystals were measured for the first time. In order to attach the HEWL crystals onto the wire, crystal growth was carried out at the air-liquid interface of the solution by the magneto-Archimedes effect. Gadolinium chloride (a paramagnetic subject) was used as a precipitant agent of crystallization. The thermal conductivity and diffusivity of the HEWL crystals at the applied magnetic field (H) of μ0H = 4.0 T and the temperature of 17.2 °C were determined to be 0.410 W/(m·K) and 3.77 × 10-8 m2/s 14 h later from the start of the crystal growth, and 0.438 W/(m·K) and 5.18 × 10-8 m2/s 20 h later, respectively. In this measurement, the concentrations of HEWL and GdCl3 were 6.53 wt% and 0.362 mol/kg, respectively, and the pH was 3.30.

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