The thermal properties of zinc · chromium spinel-chromium system were measured by flash method. The heat capacity of composite compacts changes approximately linearly with Cr content, but the thermal diffusivity was increased when a proper quantity of metallic chromium was added to the ZnCr
2O
4-Cr solidification system. A remarkable increase in thermal conductivity was observed when over 50 mass percent of Cr content. This corresponded to the proportion of ZnCr
2O
4 spinel and metallic chromium of composite compacts. And this was attributed to the electron conductivity increase due to the increase of metallic chromium in ZnCr
2O
4-Cr solidification system. The thermal expansion coefficient was increased with an increase of metallic chromium content. This was explained by the X-ray diffraction evidence that formation of continuous phase of metallic chromium in composite compacts.
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