The contents of micro constituent elements in marine invertebrates such as
Octopus, Sepia, Holothuria and
Aurelia have been investigated. The determinations of copper, zinc, cadmium and lead were polarographically conducted on the solutions obtained from their dithizone complexes which had been extracted by use of chloroform. The determinations of iron and aluminium were colorimetrically performed on their oxine complexes extracted by use of chloroform.
Octopus and
Sepia generally contain appreciable amounts of these micro constituents, and especially in their livers the quantity of copper, zinc and iron amounts to a few percent.
Holothuria contains aluminium, iron and lead in considerable quantity. The animal of lower order like
Aurelia contains very small amount of all the metals determined. Comparing with the concentrations in the sea water, most of the metals are much condensed in these animals. The atomic ratio Cu/Zn in these invertebrates is generally 0.2-0.5, but the value Fe/Al is variable and extremely larger than that in the sea water.
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