Effect of O
2 on the decolorization of indigo carmine and on the production of dissolved species such as NO
2-, NO
3-, O
3 and H
2O
2 in the treatment water by pulsed discharge in water droplet spray was investigated by controlling the O
2/N
2 ratios as carrier gases in the reactor. The decolorization rate gradually increased with rise in O
2 ratio, which reached a constant value in the range of 50% to 90% O
2 ratio and decreased in pure O
2. The maximum value was about 2 times as high as that of 20% O
2 ratio. The decolorization efficiency was not affected by gas flow rate in the range of 4 L/min to 50 L/min. NO
2- in the treatment water was only detected in pure N
2, but NO
3- was produced in O
2/N
2. NO
2- added to the treatment water was not oxidized in pure N
2, but was perfectly converted to NO
3- in O
2/N
2. These results implied that hydroxyl radical produced in gas phase does not directly contribute to the oxidation of substances in water. O
3 concentration gradually increased with rise in O
2 ratio, whereas H
2O
2 concentration decreased. In the range of 50 to 80% O
2 ratio, O
3 and H
2O
2 concentrations were approximately constant value, similar to the trend of decolorization rate. Moreover rate constants on various gas mixing ratio of O
2/N
2 were determined from the kinetics study. These results suggested that hydroxyl radical produced in the treatment water by the chain reactions of O
3 and hydroperoxy radical (HO
2·) plays an important role of the decomposition of molecules in water.
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