IEEJ Transactions on Fundamentals and Materials
Online ISSN : 1347-5533
Print ISSN : 0385-4205
ISSN-L : 0385-4205
Volume 143, Issue 1
Displaying 1-18 of 18 articles from this issue
Special Issue on Technology 2023: Review of Fundamentals and Materials Research
Special Issue Review
Paper
  • Kazuhiro Nishimura
    2023 Volume 143 Issue 1 Pages 23-30
    Published: January 01, 2023
    Released on J-STAGE: January 01, 2023
    JOURNAL RESTRICTED ACCESS

    The direction of magnetization in which the magnetic field becomes the strongest in the x-axis direction in the spherical coordinate system is used. Its magnetic field depends on the φ direction in the spherical coordinate system, i.e., strongest at the top (φ = 0) and the bottom (φ = π), and the side (φ = π ⁄ 2) becomes the weakest. Therefore, when segmenting, it was divided to include the top and the bottom parts. In addition, in order to make it an optimal segmentation, it is effective to make the range of the top and bottom divisions wide, the sides narrow, and the direction of magnetization close to the top and the bottom directions. By optimizing in this way, the magnetic field is larger than the equal division. For example, it was about 1.09 times stronger in three divisions. This was confirmed by the experiment. However, there is a problem that the demagnetic field in the center becomes strong by the optimizing. The type of division which is strong in this problem is also introduced.

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  • Takayuki Nishishita, Masashi Mitsui, Masayoshi Ishida
    2023 Volume 143 Issue 1 Pages 31-37
    Published: January 01, 2023
    Released on J-STAGE: January 01, 2023
    JOURNAL RESTRICTED ACCESS

    Solid Oxide Fuel Cells (SOFCs) generate electricity efficiently for high reaction activity and internal reforming of hydrocarbons at high temperatures, which consequently have the potential to replace conventional thermal power generations. It is expected to adjust the output with voltage whenever possible when the scale of SOFC enlarges more than the megawatt-class to reduce transmission loss. Our group aims to establish the design guideline for high-voltage insulation in high-temperature oxidizing and reducing atmospheres. This paper describes the creepage distance dependency of DC breakdown voltage in hydrogen assumed an anode environment. The authors measured the characteristics of alumina at 700 - 900°C and compared them to that in air assumed a cathode environment, which was clarified in a previous report. In both atmospheres, the results show that the breakdown mechanism follows Townsend ’s theory in a wide range; however, it affected by space charge in a region of specific creepage distances. Moreover, creepage distance to obtain the same breakdown voltage and the mechanism transition in hydrogen is approximately twice that in air. It is suggested that the mean free path and ionization index for impact ionization could govern the relationship between creepage distance and breakdown strength, regardless of the gas type, hydrogen or air.

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  • Satoshi Kurumi, Wataru Yoshino, Ken-ichi Matsuda, Kaoru Suzuki
    2023 Volume 143 Issue 1 Pages 38-43
    Published: January 01, 2023
    Released on J-STAGE: January 01, 2023
    JOURNAL RESTRICTED ACCESS

    In this paper, we report on a one-step production method of gold nanostructured films for a surface-enhanced Raman scattering (SERS) chip, expected to be an advanced device for high-sensitive molecular detection, by a pulsed laser ablation method. Surface images, taken by atomic force microscopy, revealed that the gold nanostructured film on a SiO2 substrate have dome-shaped nanostructures. Pattern of x-ray diffraction of the gold nanostructured films showed existence of an Au(111) crystalline and intensity of it was increased with increment of the laser pulses from 5000 to 15000. Optical transmittance spectra of the gold nanostructured films on SiO2 showed that significant redshift of the absorption edge from 582 to 632 nm with increasing the number of the laser pulses. To evaluate the so-called enhancement factors of the SERS chips fabricated in this study, we measured SERS activation signals from the gold nanostructured films decorated with 4-mercaptobenzoic acids by a Raman spectroscopic system equipped with two different laser beams (532 and 785 nm). Using a 785 nm wavelength laser beam, the SERS activation signals were detected clearly from the gold nanostructured film produced with 15000 pulses. From that measurement, we approximately calculated the enhancement factor for that nanostructure as 1.4×105.

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