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Volume 30 (1981)
- Issue 6 Pages 365-
- Issue 5 Pages 293-
- Issue 4 Pages 223-
- Issue 3 Pages 151-
- Issue 2 Pages 77-
- Issue 1 Pages 1-
Volume 30, Issue 6
Displaying 1-8 of 8 articles from this issue
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Masao SEYA1981 Volume 30 Issue 6 Pages 365-370
Published: December 31, 1981
Released on J-STAGE: June 28, 2010
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Masatoshi NAKAMURA1981 Volume 30 Issue 6 Pages 371-378
Published: December 31, 1981
Released on J-STAGE: June 28, 2010
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Masaki MORIMOTO1981 Volume 30 Issue 6 Pages 379-386
Published: December 31, 1981
Released on J-STAGE: June 28, 2010
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Tatsuo MIYAZAWA1981 Volume 30 Issue 6 Pages 387-391
Published: December 31, 1981
Released on J-STAGE: June 28, 2010
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Mitio INOKUTI1981 Volume 30 Issue 6 Pages 393-405
Published: December 31, 1981
Released on J-STAGE: June 28, 2010
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G. HERZBERG1981 Volume 30 Issue 6 Pages 407-421
Published: December 31, 1981
Released on J-STAGE: June 28, 2010
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R. Norman JONES1981 Volume 30 Issue 6 Pages 423-436
Published: December 31, 1981
Released on J-STAGE: June 28, 2010
JOURNAL FREE ACCESSThe author analyses the relation between organic chemistry and vibrational spectroscopy and the manner in which it has changed during the thirty year period since the Journal of the Spectroscopical Society of Japan began publication. A review of the period 1950-1960 emphasizes the early interest of organic chemists in using infrared spectroscopy to solve problems of molecular structure and qualitative analysis. This was based very largely on a classification of infrared absorption bands in terms of local group frequencies. The newer developments in instrumental analysis in the 1960's and 1970's have had both positive and negative effects on the use of infrared and Raman spectroscopy by organic chemists. This is discussed with particular reference to (proton) nuclear magnetic resonance spectroscopy. laser Raman spectroscopy and Fourier transform infrared spectroscopy. The more general consequences of the development of data analysis systems based on the use of electronic computers are also evaluated.View full abstractDownload PDF (2280K) -
Kazuo NAKAMOTO1981 Volume 30 Issue 6 Pages 437-454
Published: December 31, 1981
Released on J-STAGE: June 28, 2010
JOURNAL FREE ACCESSDuring the past decade or so, inorganic vibrational spectroscopy has made great strides with the advent of several new experimental techniques. First, the development of the metal isotope technique provided the means to make unequivocal assignments of vibrations in the low frequency region. It is currently a routine practice to obtain metal isotope data whenever definitive assignments of metal-ligand vibrations are required. Second, the matrix isolation technique became accessible to inorganic chemists as a result of the development and marketing of closed cycle helium cryocoolers. By combining various types of ovens with these cryocoolers, inorganic chemists were able to prepare a large number of unstable coordination compounds and measure their vibrational spectra in the matrix isolated state. Third, the development of gas and dye lasers together with double and triple monochromators revolutionized Raman spectroscopy. Nowadays, measurements of Raman spectra are as routine as that of infrared spectra. Resonance Raman spectroscopy is also playing a significant role in understanding the relationship between resonance-enhanced vibrational modes and the nature of excited electronic states involved. The purpose of this article is to review our contributions in these three areas using typical examples.View full abstractDownload PDF (2548K)
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