The electrical properties of ZnO ceramics were studied from their voltage-current characteristics, thermally stimulated current (TSC), and heat-treatment effects.
ZnO ceramic samples with a few mol% of insulating oxide components were prepared. After sintering at 1, 200°C in air, some of them were heat-treated at various temperatures between 450°C and 900°C in air.
In the voltage-current curves, the current varies as a function of applied DC voltage, according to the relation;
I=kVa, where α is the nonlinear exponent. The nonlinear exponent α decreased with the heat-treatment temperature in the low temperature resion, and it became the lowest around 600-750°C. But they almost recovered at 900°C.
Three TSC peaks (designated by
P1,
P2 and
P3 from low temperature side) were observed in the nonheat-treated sample. The sample heat-treated at 600°C and 750°C showed only the
P1 and
P2 peaks, the
P3 peak increased in magnitude with the increase of the biasing temperature
Tb, and it shifted toward high temperature side.
These results suggest that the electrical properties of ZnO ceramics will be associated with the phase transition of the Bi
2O
3-rich intergranular by heat-treatment.
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