In heavy oil-burning thermal power plants, NH
3 injection is frequently used to neutralize SO
x in flue gas. In order to ascertain the neutralization effect the concentration of NH
3 must be measured in the presence of high concentration of SO
2. Ultraviolet absorption spectroscopy in the 200-225 nm wavelength region is the most sensitive method to measure SO
2 and NH
3. However, as the absorption bands of SO
2 and NH
3 overlap, accurate determination of the SO
2 absorption is needed to detect the absorption due to trace NH
3. The nonlinear dependence of the absorption coefficient on the concentration, which appeared for absorption coefficients of α>0.05 cm
-1, is taken into account using a third order polynomial approximation in order to accurately determine the SO
2 absorption. An analysis procedure based on this approximation was developed. Results showed that NH
3 concentrations of about 4 ppm can be detected in the presence of SO
2 concentrations of about 1000 ppm.
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