Poly-xylyleneadipamide, made of 85 mole % m-xylylenediamine, 15 mole % p-xylylene-diamine and adipic acid, was extruded into undrawn filaments. The relationship between molecular orientation and crystallization of undrawn filaments and their mechanical properties were discussed, and the following results were obtained:
1) When undrawn filaments having the birefringence less than 3×10
-3 are dipped in water or treated in hot air, molecular chains crystallize in random orientation. On the other hand, when undrawn filaments having the birefringence more than 6×10
-3 are treated in the same way, molecular chains crystallize in oriented state.
2) When undrawn filaments are tested by the impact test method, filaments having low birefringence break at the yield point. On the other hand, filaments having high birefringence undergo plastic deformation, without breaking at the yield point.
3) The tenacity at the breaking point of undrawn filaments takes the maximum value when their birefringence is between 3 and 5×10
-3.
View full abstract