This paper intends to establish a method for estimating the detailed fine structure of amorpphous regions in polymer solids from dynamic loss tangent (tan δ)-temperature (T) curves in the temperature range where dynamic absorption (α
a; absorption) due to microbrownian movement of polymer segments appears. The amorphous region is assumed to be composed of many small particles, while the packing state of polymer segment is uniform. This small particle is regarded as a fundamental element. In order to express the distribution of elements, the distribution function of packing density
F(n) is newly introduced. The value of tan δ for the polymer sample can be expressed by the summation of the product of tan δ value and elastic modulus fraction of individual element constituting the sample. Analytical method for determining
F(n) from the experimental tan δ-T curve as well as from the apparent activation energy Δ
Ha; is established. The validity of assumption adopted in this method is ascertained by the following experimental facts: The possible change in the fine structure of amorphous regions during measurement of tan δ-T curve is practically ignorable in many cases except for Nylon 6. The temperature dependence of Δ
Ha;, calculated from
F(n) and from the WLF equation, agrees qualitatively with that directly measured. For the samples having wide
F(n), the temperature-time superposition correspondence law does not hold.
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