A theoretical equation is derived to determine the tan δ-temperature(T)curve of the system composed of a single relaxation time, and the curve is calculated. Comparison of the calculation with experimental results shows that; (1) The three-element model combining the Maxwell element with one spring parallelly is most suitable for a viscoelastic model having a peak in the tan δ-T curve. (2) The peak temperature in the tan δ-T curve,
Tmax (
k), and the apparent activation energy Δ
Ha, give the inherent half value width of tan δ-T curve Δ
T1/2(s) by the equation Δ
T1/2(s)=5.240×10
-3 Tmax2/Δ
Ha. (3) The log tan δ-T curve can be approximated by an equilateral triangle. (4) The parameter
B∞ defined by the equation
B∞=522Δ
Ha/
Tmax, is convenient for determining the mechanism of viscoelastic absorption. (5) The average Δ
T1/2(s) of various polymers is 13 deg for the absorption (α
a) related to the microbrownian movement of segment in amorphous, and 20 deg for the absorption (β
a) related to the local movement of the main chain. Thus, the value of β
a absorption is larger than that of α
a absorption. (6) A method is presented to determine the relaxation time at the glass transition temperature
Tg by Δ
Ha and
Tmax.
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