By mearsuring gas contained in open-hearth slag, the relation of such gas and hydrogen content in molten steel is studied, and it is investigated that four kinds of gas, viz., H
2O, CO, CO
2 and H
2, are contained in the slag and maintain mutually a balance represented approximately by the following formula
CO+H
2O CO
2+H
2H
2O contained in the slag is that which was absorbed from furnace atmosphere, in which 5-10% of water is usually contained. If boiling of molten steel is vigorous, CO in the slag increases and H
2O decreases.
The hydrogen content in molten steel is proportional to the partial pressure of H
2+H
2Ocontained in gas in the slag and is inversely proportional to the FeO content in molten steel. Consequently. hydrogen increases as a result of the declination of boiling activity due to the decrease of oxygen content in molten steel. Especially, by killing the molten steel for a long duration, the hydrogen content increases considerably.
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