The authors have studied on the promotion of repidity and reliability, and the simplification of the usual method The outline of precedure is as follows:-
(1) Sample is dissolved by HClO
4 (60%) sol.
(2) After phosphorus in sample is oxidized, suturated KMnO
4 sol. is added drop by drop and excess of KMnO
4 is reduced by adding of little H
2O
2.
(3) Subsequently, phosphorus is precipitated by adding of HNO
3, NH4NO
3 and (NH4)2MoO
4 sol.
(4) The following is entirely the same as the ordinary volumetric procedure.
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