A small piece of Swedish pig iron was melted down at 1250°C in the Porcelain tube passing through the purified hydrogen gas. Keeping the temperature at constant, the tube was evacuated and then hydrogen was refilled. The procedure was repeated from 1 to 40 times. With. an inerease of the times of repetition, graphite flakes grew up longer in length and the content increased. When repeated to a certain extent, graphite flakes became shorter in length and the content decreased. At last, graphite disappeared and the long fine cementite crystals appeared. After the pig iron was melted and purified with this procedure, the hydrogen was replaced respectively by CO, CO
2, O
2 and N
2 and allowed to coal. All of CO, CO
2 and O
2 gave rise to the fine eutectic graphite structure and in the cases of the first two the combined carbon was little formed but in the last the secondary cementite existed in pearlite. N
2 gave rise to the straight graphite flakes and e ground mass was wholly pearlitic. When CO coexisted with H
2 or N
2, or with both of them it promoted the further growth of graphite flakes and N
2 in this case made the graphite flakes straight also.
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