A fundamental research on the inorganic binders produced in Japan was made in this report. The samples used in this experiment belong to the following various kinds of clay produced in Japan.
Montmorillonite group····Bentonite of Hōjun brand
Kaolite group····Kibushi clay
Secondary mica group····Red clay of Haru-machi
Mixed type····Clay of Mitsuishi
These clays were submitted to various analyses such as chemical analysis, X-ray analysis, electron microscopic analysis and differential thermal analysis, while their swelling capacity, base exchange capacity, pH. value and others were measured, the result of which was discussed relatively with binding power.
In the next place, the change in the binding power on heating above 100°C was experimented with the synthetic sand to which four kinds of clays were added, and have taken the following results.
1) Any clay belonging to each group considerably loses its binding power when it is heated up to the temperature where combined water begins to discharge.
2) The green strength of the synthetic sand to which the clays heated to various temperatures are added changes as, follows:
bentonite····The strength lowers in a marked degree by the heating above 600°C, but makes little change up to 500°C.
The strength of both Kibushi clay of kaolite group and Harumachi clay of the secondary mica group gradually falls off with heating, the former making a sudden drop at 450°C and the latter above 400°C,
3) The dry strength of the above-mentioned synthetic sand is subject to the effect of specimen drying temperature.
The synthetic sand, due to the effect of to Bentonite, shows no change in dry strength under the drying temperature less than 400°C, but drops its strength a little at 500°C and considerably at above 600°C.
In case of the clay belonging to the other group, the strength of it gradually decreased with the rise of drying temperature, showing minimum strength at a certain temperature and at a temperature higher than that, the strength rose again, coming down at above 650°C.
The drying temperature showing this minimum strength was 350°C with Harumachi-clay, 450°C with Kibushi clay and 450°C with Mitsuishi clay.
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