The reaction between the molten Ni-base super alloy for single crystal casting, Alloy 454, and the high purity mullite on the market was examined at 1,500°C, 1,540°C and 1,580°C under the reduced pressure about 2×10
-10 Torr. The reacted layer is produced to 10-16
μm at 1,500°C, 18-27
μm at 1,540°C, 38-52
μm at 1,580°C. The main product of the reaction is considered to Al
2O
3 from the result of X-ray microanalysis. Some of the products are contaminated as the inclusion at the near side of the reacted layer in the obtained ingot. Probably, the cause of reacting the mullite specimen with the molten alloy may be existing the mullite solid solution in the specimen, especially containing higher SiO
2 than the stoichiometric composition, which presumed to come from the problem of the preparing method of the raw material and the occurrence of the composition shifting while the contact with the molten alloy for a long time at high temperatures.
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