It is well known that Ca-Si alloy is effective for spheroidizing graphite in cast iron. However, an excellent effect could hardly be anticipated in actual practice by an addition of the alloy alone. So it was investigated in details and it was cleared that Ca-Si alloy, when added to a molten iron, formed on the surface of the alloy the shell composed of
α-Ca
2SiO
4 by air and CaC
2 by molten iron. As the shell has a very high fusion temperature, it prevented the alloy from contacting with a molten iron. The addition of flux to the alloy is, therefore, very effective for keeping the alloy from forming the shell having a high fusion temperature or for sweeping away the shell formed.
Then the effects of various salts as a flux were investigated and the following results were obtained :
(1) The fluorides were more effective than the chlorides of the same element.
(2) Mg salts were most effective and Na salts and Ca salts were next to it in the order.
(3) The composed fluxes that NaF, NaCl or CaCl
2 were fused respectively into CaF
2 were more effective than CaF
2 , base salt.
(4) The effect of MgF
2 as a flux decreased by fusing NaF, NaCl or CaCl
2 respectively into it.
Furthermore, the mechanism of the fluxes to promote spheroidizing graphite Ca-Si alloy was investigated. The results obtained were as follows :
(1) The salt itself has little effect to the spheroidizing graphite.
(2) The addition of Ca-salts with Ca-Si alloy is effective only for keeping the alloy from forming the shell having high fusion temperature or for sweeping away the shell formed.
(3) In case of addition of Mg-salts with Ca-Si alloy, besides the above effect, Mg-salts help the spheroidizing graphite by following reaction :
The salts react with Ca, which is isolated from Ca-Si alloy by dissolving Si-component of the alloy into molten iron, and set free Mg, producing Ca-salt.
(4) Na-salts set free Na, which spheroidizes graphite, on the same principle, but the effect of the salts is weaker than that of Mg-salts, for Na has a high vapor-pressure at the reaction temperature.
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