By adding a small amount of boron, cast iron with a characteristic microstructure (fine mottled structure) can be prodused. In order to clarify the process by which such a characteristic structture can be obtained, authors studied the changes in microstructure and the cooling curve, when different amounts of boron were added to Fe-C and Fe-C-Si-Mn melts. Moreover, cast specimens which were composed of three cylindrical parts with different diameters (40, 20, 10mm) were made from cast iron with various boron contents, and the number or the shape of austenite-graphite entectic cells was counted. The results obtained can be summarized as follows :
(1) By adding boron to a hypoeutectic cast iron melt, the primary austenite arrest temperature in the cooling curve can be lowered, and the carbon content of the eutectic liquid can presumably be lowered also.
(2) When the amount of boron is increased, the progress of austenite-graphite eutectic solidification slows down; and in mid-progress, austenite-carbide-eutectic solidification takes place.
(3) As boron content increases, the structure of Fe-C-B alloy changes from a normal gray cast iron structure to a white cast iron structure. As an intermediate structure, white cast iron structure contatining fine graphite eutectic cells or irregularly shaped lump graphite can be observed. In Fe-C-Si-Mn-B alloy, a greater amount of graphite can be observed compared to Fe-C-B alloy, and a fine mottled structure with flake graphite and carbide can be obtained.
(4) Addition of boron increases the number of austenite-graphite eutectic cells and tends to make the shape of the cells irregular.
(5) Boron seems to slow down the growth rate of austenite-graphite eutectic cells, and seems to be enriched in the remaining liquid as eutectic solidification proceeds.
These results would explain the specific process and microstructure of boron containing cast iron.
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