It has been shown in authors' previous studies that the dendritic structure of Al-solid solution in Zn-Al binary alloys may be refined considerably by adding small amounts of Zr, Ti, Mn or Ni. Tests were carried out to investigate in detail the effect of those elements on dendritic structure. By Zr addition, nodular-like structures were observed in alloys of 0.05-0.28%Zr addition which grew slowly with the increase in the temperature drop. Dendrite arm lengths in every composition increased rapidly in the initial stages of freezing. Secondary arm cell size and arm spacing increased gradually as the temperature drop increased and the growth rate of dendrite cell in alloys of 0.28%Zr addition was greater than those of other composition alloys. In case of Ti addtion, petaloid-like dendritic structures were observed in alloys of 0.05-0.5% Ti addition. The growth of dendrite, and changes of arm length, cell size and arm spacing were nearly the same as Zr addition alloys. The growth of dendrite in 0.25% Tialloy was less than that of other composition alloys. With regard to Mn addition, the dendrite shape factors were nearly the same as Zr and Ti addition alloys. In case of Ni addition, the growth of the primary dendrite was disturbed by increasing the amount of addition. The secondary dendrite arm length increased rapidly until the temperature drop of approximately 30°C. Secondary arm cell size and arm spacing increased gradually as the temperature drop increased and the dendrite arm lengths grew especially remarkably in 1.0%Ni alloys. The Zr and Al concentrations of dendrite in the freezing range of Zr addition alloy which remarkably refines dendritic structures were measured. It was recognized that Zr was slightly enriched at the circumference of the secondary arm cells in 0.1%Zr alloy was greater than that of 1.0%Zr alloy.
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