The spongy cast metal can be produced by a new process, that is, pressure casting with the infiltration of molten metal into pores of sintered particles, followed by dissolving the particles in a solvent. The spongy cast stainless steel (Fe-18 % Cr-8 % Ni) with the porosity between 50 and 55 % was obtained by making use of MgO or CaO particles.
Liquid phase sintering of particles with a small amount of B
2O
3 as a sintering additive was performed at 1638 K (MgO) and 1748 K(CaO) for 3.6 ks in the air. B
2O
3 did not reduce the solubility of the particle in a solvent.
The critical preheating temperatures of sintered particles required for the pressure casting at 1873 K were 1523 K for sintered MgO with the packing density of 50 % and 1373 K for sintered CaO with that of 55 % . Since sintered particles preheated in a ceramic-wool case were used, it was possible to avoid sticking of casting to the mold in consequence of relatively low preheating temperature (∼393 K).
MgO particles in the composite was possible to dissolve in HN0
3, and CaO particles dissolved in HN0
3, NH
4Cl and chelating agent. It is the most practical way to use CaO particles and HN0
3 as a solvent to produce the spongy cast stainless steels.
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