The distribution of Cr, Mn, Mo and V in hypoeutectic white cast iron was investigated with an electron probe microanalyser. The specimens were made from castings (30mm
φ×70mm) solidified unidirectionally in exothermic molds on a water-cooled copper chill plate. The carbon content of the specimens varied from 1.8% to 3.8% and the content of each alloying element was about 1%.
It was found that the concentration of each alloying element in dendrites took a minimum value at the core and went up gradually towards the outside, and that it was much higher in the eutectic cells. Microsegregation was more remarkable when carbon content was low. The effective distribution coefficients (K
e) of Cr, Mn, Mo and V against the primary austenite were an less than unity, and decreased proportionally with increase in carbon content. The K
e value became larger in the order of Mo, V, Cr, Mn. The concentration of Mo and V in primary austenite at larger solid fractions were remarkably lower than the value calculated from the nonequillibrium freezing equation
5). The main reasons could be the variation of K
e during solidification and the precipitation of their carbides.
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