For the investigation of influence of gas atmosphere and alloy elements on burning reaction at cast steel-mold inteiace, mixed CO and CO
2 gases were used for atmosphere, and carbon steel, high manganese steel, high chromium steel and nickel-chromium steel were used for alloy steels. The following are the results. (1) In mixed CO and CO
2 gases, the metal-mold interface reaction increases with incresing CO
2 gas ratio. The rection is more remakable at 1,400°C than below 1,350°C. When CO
2/ (CO
2+CO) ratio is 0∼10%, steel does not react with SiO
2 at all because of stronger reducing atmosphere. (2) As for the influence of alloy elements on FeO-SiO
2 reaction, manganese promotes the reaction and chromium restrains it, but the influence of nickel is not clear. (3) From the observation of microstructure, results of X-ray diffraction and X-ray microanalysis, it is considered that the reaction products are mostly composed of fayalite, and that manganese forms manganese silicates in the reaction products, while chromium is present as chromium oxide in the oxide layer of the surface of steel and restrains the emergence of FeO.
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