The authors have pointed out
1) previously that the differences in the characteristics between induction-melted iron and cupola-melted iron and the modification of properties followed by changing steel ratio in raw materials closely corresponds to the nitrogen content in iron. Furthermore, authors have determined the nitrogen content of various carburizers and found that the nitrogen content varied form a trace amount up to a few percent. From these results, it may be predicted that the properties of iron carburized with different kinds of carburizers alters. The present work was conducted to verify our prediction and to clarify the effect of the various kinds of carburizers on the properties of iron melted.
In this investigation, electrode graphite (N : trace) and pitch coke (N; 0.63%) were used as carburizers and their influences on a comparably high carbon equivalent, 4.0 to 4.8, induction-melted iron was studied. Melting of 100kg charge with high steel ratio was done in a medium frequency indudtion furnace with magnesia lining.
The following results were obtained.
(1) Iron carburized with pitch coke ( hereafter referred to as p-iron) showed higher tensile strength and hardness than the one with electrode graphite (hereafter referred to as e-iron). These differences in strength of the two iron became more evident especially when the holding time of the melt was short. The strength of p-iron was as much as twofold of that of e-iron.
(2) The chilling tendency was higher in p-iron than in e-iron, the difference of which in-creased as the carbon equivalent became higher.
(3) As for the thin section castings prepared from a melt held for a long time, e-iron may became harder than p-iron.
(4) The nitrogen content of p-iron melt was very high when the holding time of melt was short and it decreased with time. On the other hand, the nitrogen content was generally low in e-iron melt and changed little with time. The variation of nitrogen content with time corresponded well with the variation of strength in iron.
(5) E-iron tended to show a well prolonged A-type graphite structure. On the other hand, p-iron tended to show a mixed structure of A-, D- and E-type graphite.
(6) P-iron held for a short time in melting tended to show pearlite matrix structure. But p-iron held for a long time and the e-iron showed a ferrite matrix structure.
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