Sand mold bonded with sodium silicate and dicalcium silicate has more merits than CO
2 sand mold. The demerit of CO
2 sand mold is that the mold bonded with sodiumsilicate has a difficulty in collapsibility because of its too high residual strength after heating at high temperatures. Generally speaking, the collapsibility of the mold can be improved by using such sodium silicate as having high mol-ratio or adding organic compounds to the sand. Then, a study has been made in order to clarify how the collapsibility of dicalcium silicate sand mold is influenced by such factors as the mol-ratio and specific gravity of sodium silicate solution. Further, the influence of the addition of alkali earth oxides and carbon aceous compounds having a tendency to thermal decomposition on the collapsibility of the mold has been made with the cases of castings having various thicknesses. The experimental results were: 1) The collapsibility of mold was dependent upon the residual strength of the mold. However, this could not be applied to the case of heavy castings in which fusion took place. 2) The higher the strength at room temperature, the higher the strength of the mold at high temperatures. Hence, to obtain the best collapsibility it was preferable to reduce the strength of the mold to the lowest limit of strength at which molding could be performed, namely to the extent of 10 to 15kg/cm
2 3) The less the amount of sodium silicate addition, the lower the residual strength. 4) The residual strength of mold was reduced by increasing the mol-ratio and decreasing the concentration of the sodium silicate solution. 5) The residual strength could be reduced by adding bentonite or carbon aceous compounds. 6) Addition of magnesium oxide had favourable effect upon the reduction of the residual strength and collapsibility at comparatively lower temperature range from 100 to 400°C. However, no improvement could be realized at higher temperature from 800 to 1,000°C. 7) The favourable influence of magnesium oxide addition was more remarkable at temperatures of wider range in case carbon aceous compounds were added. The most favourable contents of magnesium oxide and carbon aceous compounds were 0.5 and 1.0% respectively.
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