Petroleum such as oil and gas generated from kerogen under low temperature will migrate primarily from source rocks to reservoir rocks. Much water will be necessary as a carrier of these hydrocarbons especially in the case of oil. Many investigators have considered that the expulsion of interlayered water from montmorillonite and mixedlayered mineral by transformation during diagenesis would be most important as a carrier of oil.
The writers, however, studied in detail the expulsion mechanisms of interlayed and interstitial water and the change of pores and grains (especially minerals) in argillaceous rocks during each stage of diagenesis, and examined the depth and temperature on generation of hydrocarbons in the various sedimentary basins in Japan and elsewhere. As a result, we reached another conclusion different from their theory on primary migration of petroleum as follows.
During the first stage of diagenesis (early compaction stage), argillaceous rocks have porosity beyond 30 per cent and generation of oil is not vigorous in general. Biochemical methane generated earlier will escape considerably by rapid dewatering of interlayered and interstitial water. During the early third stage of diagenesis (recrystallization stage), argillaceous rocks have 10 to 5 per cent porosity and generation of hydrocarbons is active in usual. Interlayered water by the transformation from montmorillonite to mixedlayered mineral will expel. However, the expelled water is small in content and also is difficult to migrate outside because of the lack of proper paths in the rock. Therefore, almost of oil generated during this stage could hardly migrate, although gas could move. During the late third stage of diagenesis, argillaceous rocks have porosity below 5 per cent and generation of oil become weak while formation of thermochemical methane is still active. Migration of oil from source rock will be quite difficult as the content of carrier water is very small.
On the contrary, during the second stage of diagenesis (late compaction stage), porosity of argillaceous rocks is between 30 and 10 per cent and content of carrier water is enough for migration of oil. Because dewatering of interstitial water is still active and expulsion of crystalline water from zeolite lattice and those of interlayed water from montmorillonite lattice are considerably vigorous with the progress of diagenesis. Almost the same content of interstitial and interlayered water will expel. Oil could migrate outside through the pores between grains though their genera tion was not so active in argillaceous rocks of Japan generally. Moreover, from the petrophysical viewpoint of reservoir rocks, it is reasonable to consider the migration of oil could occur during this stage.
From this conclusion, it is expected that the big oil will move during the period when the active generation of oil corresponds with the primary migration of water. The stage of primary migration of carrier water in Japanese oil fields is considered to be 1, 500 to 2, 800m at burial depth. Therefore, the possibility of formation of big oil pools will be high at the area where the geothermal gradient is between 3.0 and 3.5°C/100m. Previous evaluation of oil production in the exploration area is possible by the examination of geothermal gradient and vertical change of porosity in argillaceous rocks.
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