It was pointed out that the heating rate in annealing white cast iron, Whose composition is of malleable cast iron (2.6%/C, 0.87/Si, 0.55%Mn, 0.145%P, 0.069/S), influences its graphitization phenomena remarkably, and the reason of which was discussed. The faster the heating rate to the annealing temperature is, the larger both the primary and the secondary graphitization velocity becomes. This effect can be observed in cast iron both in cast state and in quenched one; in the former case, the effect is strongly observed and in the latter weakly. When the subsequent annealing treatment is constant, slow heating to the temperature results in less graphitization amount than by rapid heating. Accordingly, less graphitization amount may be observed even when the total heating time is longer, which is caused by slow heating. Furthermore, it must be noted that rapid heating of the white cast iron results in the production of smaller and numerous graphite particles.
The above phenomenon is similar to the recrystallisation phenomenon of plastically worked metals by heating, althongh the two phenomena are quite different in their natures.
The quenching degree of the white cast iron may be considered to correspond to the working degree, and the graphite particle size to the recrystallized grain size. The recrystallized grain size of worked metals becomes large as the heating rate is small, and vice versa. In the similar way, the graphite particle size produced by annealing the white cast iron becomes large when the heating rate is small and small when it is large. But, the higher the graphitizing temperature of the white cast iron is, the coarser the graphite particle size becomes, which is caused by the growth of cementite before graphitization begins, and it is dissimilar in this point to that the recrystallized grain size becomes finer as the recrystallizing temperature rises.
The above phenomenon leads to the following conclusion on the practice of malleable cast iron making; the so-called short annealing cycle of 15_??_20 hrs. not only makes the temperaturé reach rapidly the annealing one, but also causes the rapid heating rate itself in the cycle to accelerate the graphitization velocity. Furthermore, rapid heating increases the graphite neucleus number, hence fine graphite particles of uniform distributiorn lead to improve the toughness of castings.
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