The writer has already published a series of reports on the diffusion of powdered metals or sometimes of non-metals exhibiting metallic properties (Zn, Sh, Al, Sn, Cr, Si, Mn, Ti, Be, W, Mo, V, Ta, B), that is, metallic cementation in technical words on other solid metals, such as Fe, Ni, Cu, etc., at various high temperatures. For the present work the cementation of cadmium, by making use of diffusion agent containing 25% Cd+65% Al
2O
3+10% CdCl
2, on copper, nickel and silver at various temperatures between 250° and 500° for copper, 250° and 600° for nickel, or 270° alld 600° for silver, for 1 to 5 hours was executed. For the surface layer of the cemented specimens, the measurement of Vickers hardness and depth of penetration, microscopic examination, chemical analysis as well as corrosion test by some acids were carried out. From the experiment the following facts were found: Cadmium diffuses into the metals above mentioned at a temperature lower than. 270°, - and the rate of diffusion increases as the temperature rises, The relation between the weight increase of the specimen (
ΔW) or the depth of penetration (
P) and the absolute temperature of cementation (
T) or the time (θ) required for the treatment is given by an exponential function
ΔW=αe, -b/T or
ΔW=ae
tθ, where a and bare different constants in each case. Also the log
ΔW (or log
P) --1 /
T×10
4 curves show an abrupt change at the temperature corresponding to the melting point of cadmium. The cemented surfaces of copper, nickel, and silver are harder than the original material. The cemented surfaces of copper and silver resist against both diluted sulphuric and hydrochloric acids, while that of nickel is readily attacked even by the diluted solution of the strong acids.
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