The volume changes of pure aluminium (99.74%), Al-Cu and Al-Si alloys during solidification have been studied by using the KCl+LiCl bath. The main results of the present investigation are as follows:-
(1) The specific volume (specific gravity) of the molten Al at 750-659° agrees with the result obtained by Edwards and Moorman, the volume shrinkages during solidification being 0.0260 cc or 6.21%.
The linear shrinkages from 750° to 21.5° from 750° to 650° (solid) and from 650° (solid) to 21.5° (solid) are respectively 4.32%, 2.58% and 1.85%. The latter value (1.85%) nearly agrees with those obtained by extensometer by the previous investigators.
(2) In the volume shrinkage vs composition curve of the Al-Cu system, alloy of 94.3% Al (max. solidification interval) has the max. shrinkage and then it gradually decreases to 0.0140 cc or 4.44%, at eutectic (Cu 33%) and to 0.0085 cc, or 3.12%, at the composition of CuAl
2 (Cu 54.1%).
In the CuAl
2 side, there is no max. point, because the effects of the solid (CuAl
2) and liquid contractions during solidification are negligibly small compared with the shrinkage of the primary CuAl
2 on solidification.
(3) In the volume shrinkage vs composition curve of the Al-Si system, a max. point of shrinkage exists at 1.7% Si (max. solidification interval) and then it rapidly decreases to 0.0140 cc or 3.39% at 12% Si (Silumin) and to zero at 25.5% Si; the alloys over 25.5% Si, on the contrary, expands during solidification. This rapid effect of decreasing shrinkage by the Si is attributed to the expansion of the Si during solidification which fact has been observed first by the present author.
(4) Among the volume shrinkage of pure aluminium, Al 90 Cu 10%, Al 97% Si 3%, and Al 88% Si 12% (Silumin) alloys, Silumin has the smallest value and also it has the simplest shrinkage curve during solidification.
The specific gravity of pure aluminium decreases by addition of Si in the solid state butincreases in the liquid state.
This phenomenon is attributed, as already stated, to the expansion of Si during solidification.
(5) The expansion of Si during solidification at 577° (the eutectic temp. of the Al-Si system) has been calculated by the mixture rule from the bases of shrinkage of Silumin. From this calculation, the expansion of Si at 577° was found to be 0.066 cc or 13.6% which is quite noticeably larger than the other metals.
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