Characteristics and reaction mechanisms of N
2O formation/destruction in high-temperature pulverized coal combustion are studied experimentally and theoretically. The experimental results show that N
2O is mainly formed during the initial stage of volatile matter combustion, but that the N
2O concentration at the exit of the furnace reaches a low value. The maximum N
2O concentrations in different types of coal depend on the temperature gradient, the content of volatile matter and the flame structure around coal particles. N
2O concentration at the exit increases with increasing air ratio. By numerical analysis of combustion behavior using a single-particle combustion model, it becomes clear that N
2O is mainly produced by NH (formed by the decomposition of NH
3) and N
2 in the initial volatile matter combustion region, after which N
2O is formed by NCO produced by the oxidation of HCN ; however, N
2O is decomposed by H radicals.
抄録全体を表示