Vibrational Raman spectra of H
2O and CO
2 were theoretically obtained for the experimental use in temperature determination in flames. The variation of half-value width of H
2O spectrum was used to evaluate the temperature; the relative intensity of the (0, 0
0, 0)⇾(1, 0
0, 0) transition scattering to the (0, 1
1, 0)⇾(1, 1
1, 0) was correlated to the temperature of CO
2. These theoretical predictions are compared with the experimental measurements in H
2 diffusion flames. Rotational Raman spectra of N
2 and CO
2 were also studied by the theoretical predictions based on the correlation of half-value width of spectra to gas temperature, and the results are discussed in comparison with the experimental observations.
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