When 3×10
-3 M L-ascorbic acid (AA) and erythorbic acid (EA) in 50ml of 3.6×10
-3 M HCl solution (pH 2.3) containing 3×10
-3 M Fe
2 (SO
4)
3 were treated in the oxygen gas flow at a rate Of 3.3ml/sec. at 25°C, the amounts of remained AA and EA after 20min were 79.6 (±2)% and 3.7 (±0.5)% of the initial amounts respectively.
The effect of ferric ion on the decomposition of AA and EA was remarkable and accelerated definitely by lowering the pH value to 1.4.
The rate of the decomposition of these acids was also affected to some extent by the presence of neutral salts in the reaction mixture.
The difference of the decomposition rate between AA and EA is so definitely and highly reproduciable that a potential of a new method of simultaneous determination of these acids within the level of 2.5×10
-3 to 3.5×10
-3 M was suggested.
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